demeclocycline → HCID 131719400, compound

HRID 1898748Notes

Reaction equation

HRID 1898748 reaction equation
[CH3:1][N:2]([C@@H:4]1[C:22](=[O:23])[C:21]([C:24]([NH2:26])=[O:25])=[C:20]([OH:27])[C@:19]2([OH:28])[C@H:5]1[CH2:6][C@H:7]1[C:16]([C:17]2=[O:18])=[C:15]([OH:29])[C:14]2[C:9](=[C:10]([Cl:31])[CH:11]=[CH:12][C:13]=2[OH:30])[C@H:8]1[OH:32])[CH3:3]>CN1C(=O)CCC1>[CH3:3][N:2]([C@@H:4]1[C:22](=[O:23])[C:21]([C:24]([NH2:26])=[O:25])=[C:20]([OH:27])[C@:19]2([OH:28])[C@H:5]1[CH2:6][C@H:7]1[C:16]([C:17]2=[O:18])=[C:15]([OH:29])[C:14]2[C:9](=[C:10]([Cl:31])[CH:11]=[CH:12][C:13]=2[OH:30])[C@H:8]1[OH:32])[CH3:1].[CH3:3][N:2]1[C:24](=[O:25])[CH2:21][CH2:22][CH2:4]1

Participants

3

Reactant 1

HCID 54680690demeclocycline

Product 1

HCID 131719400HCID 131719400, compound

Reagents, catalysts & solvents 1

HCID 13387N-methyl-2-pyrrolidoneSolvent

Procedure

One point five (1.5) g (0.01 mole) of DMcT monomer powder were dissolved in 5 g of NMP to obtain a yellowish transparent viscous DMcT-NMP solution. To this solution, 2.5 g (0.015 mole) of polyaniline powder in a de-doped reduced state ("ANILEAD" available from Nitto Denko Corp., Japan) were added and the combined solution was then heated at 80° C. in a sealed container, whose inner atmosphere was substituted by an inert gas, to obtain a black purple liquid.

Sources & evidence

ORD record
ord-5fc9ade5d4114e549785e45ecb023f5f
Source dataset
uspto-grants-1996_11
Patent number
US05571292

Reaction notes

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