2-Butoxyethanol → HCID 15020137, compound

HRID 1898768Notes

Reaction equation

[CH2:1]([O:5][CH2:6][CH2:7][OH:8])[CH2:2][CH2:3][CH3:4].[H-].[Na+].Br[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][C:17]([OH:19])=[O:18]>>[C:17]([OH:19])(=[O:18])[CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][O:8][CH2:7][CH2:6][O:5][CH2:1][CH2:2][CH2:3][CH3:4]

Participants

Reactant 3

HCID 81332-Butoxyethanol

HCID 202106-Bromohexanoic acid

HCID 24758Sodium hydride

Product 1

HCID 15020137HCID 15020137, compound

Procedure

Illustratively, 2-butoxyethanol can be reacted with sodium hydride and the resulting alcoholate reacted with 6-bromohexanoic acid to give 7,10-dioxatetradecanoic acid. So also, 2-ethoxyethanol can be reacted with sodium hydride and the resulting alcoholate reacted with 8-bromooctanoic acid to provide 9,12-dioxatetradecanoic acid.

Sources & evidence

ORD record: ord-23744eeceab94670bf6fb6ee8bec948d
Source dataset: uspto-grants-1996_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05571689

Reaction notes

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