HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Bromopropane → HCID 23373111, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Bromopropane | HCID 7840 | — |
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | 2-Chloro-3-methyl-4-nitrophenol | HCID 13147355 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 23373111 | HCID 23373111 | 44.8% |
Reaction Steps
Treatment of 2-chloro-3-methyl-4-nitrophenol (15.5 g, 82.7 mmol) with sodium hydride (50%, 4.37 g, 91.0 mmol) and n-propyl bromide (11.2 g, 91.0 mmol) in DMF (300 ml) and subsequent workup as described in 1 (a) gave 2-chloro-3-n-propyloxy-6-nitrotoluene (8.50 g), m.p. 42°-3° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05571833 |
| Source dataset | uspto-grants-1996_11 |
| ORD ID | ord-b0963d4f8b4c41aba0a360e774a3a63a |
| Source note | uspto-grants-1996_11 |