Methyl Acrylate → HCID 18674570, compound

HRID 1901148Notes

Reaction equation

HRID 1901148 reaction equation
[C:1]([O:5][CH3:6])(=[O:4])[CH:2]=[CH2:3].[C:7]([O:12][CH2:13][CH:14]1[O:16][CH2:15]1)(=[O:11])[C:8]([CH3:10])=[CH2:9]>>[C:1]([O:5][CH3:6])(=[O:4])[CH:2]=[CH2:3].[CH2:13]([O:12][C:7](=[O:11])[C:8]([CH3:10])=[CH2:9])[CH:14]1[O:16][CH2:15]1

Participants

3

Reactant 2

HCID 7294Methyl AcrylateHCID 7837Glycidyl methacrylate

Product 1

HCID 18674570HCID 18674570, compound

Procedure

Using methyl acrylate (21.5 g, 0.25 mole) and glycidyl methacrylate (14.2 g, 0.10 mole), the polymerization was carried out in the same manner as described in Synthesis Example 12, (1). The precipitate was filtered and dried under reduced pressure to give 21.0 g of poly(methyl acrylate/glycidylmethacrylate) as a colorless viscous oil having Mw 35000 and Mn 18000 (GPC with polystyrene calibration). The composition of the polymer was found to be methyl acrylate unit and glycidyl methacrylate unit in molar ratio of ca. 5:2 based on 1HNMR analysis.

Workup

  1. filtrationThe precipitate was filtered
  2. customdried under reduced pressure

Sources & evidence

ORD record
ord-e6b12c60b8244427aaf759340c8b3669
Source dataset
uspto-grants-1996_11
Patent number
US05576359

Reaction notes

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