Phenol → HCID 20514529, compound

HRID 1902583Notes

Reaction equation

HRID 1902583 reaction equation
Cl[C:2]1[CH:7]=[C:6](Cl)[C:5]([Cl:9])=[CH:4][C:3]=1[N+:10]([O-:12])=[O:11].[C:13]1([O-:19])[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1.[K+].[C:21]1([OH:27])[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1>>[Cl:9][C:5]1[C:6]([O:19][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[CH:7][C:2]([O:27][C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)=[C:3]([N+:10]([O-:12])=[O:11])[CH:4]=1

Participants

4

Reactant 3

HCID 996PhenolHCID 69832,4,5-TrichloronitrobenzeneHCID 23670670Potassium phenoxide

Product 1

HCID 20514529HCID 20514529, compound

Conditions

Temperature
165 °C

Procedure

A mixture of 1 mol of 2,4,5-trichloro-1-nitrobenzene, 2 mols of potassium phenolate and phenol was heated for 1 hour at 165° C., and the reaction product was isolated as described in Example A(a), yielding the title compound, m.p. 95° C. (recrystallized from ethanol).

Workup

  1. customthe reaction product was isolated
  2. customyielding
  3. customthe title compound, m.p. 95° C. (recrystallized from ethanol)

Sources & evidence

ORD record
ord-2897972a2d1442288e8cca2d4b894d27
Source dataset
uspto-grants-1982_12
Patent number
US04364875

Reaction notes

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