Ethylenediamine → HCID 12881157, compound

HRID 1902591Notes

Reaction equation

HRID 1902591 reaction equation
[Cl:1][C:2]1[C:7]([O:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)=[CH:6][C:5](OC2C=CC=CC=2)=[C:4]([N+:22]([O-:24])=[O:23])[CH:3]=1.[NH2:25][CH2:26][CH2:27][NH2:28]>O1CCOCC1>[ClH:1].[Cl:1][C:2]1[CH:3]=[C:4]([N+:22]([O-:24])=[O:23])[C:5]([NH:25][CH2:26][CH2:27][NH2:28])=[CH:6][C:7]=1[O:8][C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1

Participants

4

Reactant 2

HCID 3301EthylenediamineHCID 20514529HCID 20514529, compound

Product 1

HCID 12881157HCID 12881157, compound

Reagents, catalysts & solvents 1

HCID 312751,4-DioxaneSolvent

Conditions

Temperature
70 °C

Procedure

6.83 gm of 6-chloro-4-nitro-1,3-diphenoxy-benzene were dissolved in 15 ml of dioxane, an excess of 1,2-diamino-ethane was added to the solution, and the mixture was heated for 12 hours at 70° C. Thereafter, the reaction mixture was worked up as in Example 3, and the reaction product was purified by recrystallization from ethanol. 6.1 gm (88% of theory) of the white crystalline compound of the formula ##STR10## having a melting point of 255° C. (decomp.) were obtained.

Workup

  1. customthe reaction product was purified by recrystallization from ethanol
  2. customwere obtained

Sources & evidence

ORD record
ord-11234b6017404619baa34aa087991ffa
Source dataset
uspto-grants-1982_12
Patent number
US04364875

Reaction notes

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