Nitroethane → HCID 54050540, compound

HRID 1902661Notes

Reaction equation

HRID 1902661 reaction equation
[CH2:1]([C:5]1[CH:12]=[CH:11][C:8]([CH:9]=O)=[CH:7][CH:6]=1)[CH2:2][CH2:3][CH3:4].[N+:13]([CH2:16][CH3:17])([O-:15])=[O:14].C(N)CCC>C(O)C>[CH2:1]([C:5]1[CH:12]=[CH:11][C:8]([CH:9]=[C:16]([N+:13]([O-:15])=[O:14])[CH3:17])=[CH:7][CH:6]=1)[CH2:2][CH2:3][CH3:4]

Participants

5

Reactant 3

HCID 6587NitroethaneHCID 8007ButylamineHCID 709884-Butylbenzaldehyde

Product 1

HCID 54050540HCID 54050540, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A stirred solution of 4-butylbenzaldehyde (13.5 g), nitroethane (9.0 ml) and butylamine (1.6 ml) in ethanol (20 ml) was heated under reflux for 6 hours and evaporated. The residue was distilled under vacuum to give 1-(4-butylphenyl)-2-nitropropene (bp 124°-125° C./0.15 mm).

Workup

  1. temperatureunder reflux for 6 hours
  2. customevaporated
  3. distillationThe residue was distilled under vacuum

Sources & evidence

ORD record
ord-9d78cbf07f6042fd9b5a90e5018b7d7e
Source dataset
uspto-grants-1982_12
Patent number
US04364956

Reaction notes

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