HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 13135604, compound → HCID 70478116, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 13135604 | HCID 13135604 | — |
| Catalyst | Chlorotris(triphenylphosphine)rhodium(I) | HCID 84599 | — |
| Product | HCID 70478116 | HCID 70478116 | 78.7% |
Reaction Steps
1.0 g of 17-ethoxyacetoxy-11β,21-dihydroxy-6α-methyl-1,4-pregnadiene-3,20-dione is hydrogenated as described in Example 19 with 700 mg of tris(triphenylphosphine)rhodium(I) chloride. After the reaction mixture has been worked up and purified, 790 mg of 17-ethoxyacetoxy-11β,21-dihydroxy-6α-methyl-4-pregnene-3,20-dione is isolated.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04435390 |
| Source dataset | uspto-grants-1984_03 |
| ORD ID | ord-655b7c333f09466da6596f3a4933101a |
| Source note | uspto-grants-1984_03 |