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HRID1903063

反应详情

EQUATION

反应方程式

HRID 1903063 的结构方程式

REACTANTS

反应物

2
结构：COCC(=O)Cl
HCID96623

Acetyl chloride, methoxy-

C3H5ClO2

结构：C[C@H]1C[C@@H]2[C@H]([C@@H](O)C[C@@]3(C)[C@H]2CC[C@]3(O)C(=O)CO)[C@@]2(C)CCC(=O)C=C12
HCID102147

6α-Methylhydrocortisone

C22H32O5

PRODUCTS

生成物

1
结构：COCC(=O)OCC(=O)[C@@]1(O)CC[C@H]2[C@@H]3C[C@H](C)C4=CC(=O)CC[C@]4(C)[C@H]3[C@@H](O)C[C@@]21C
HCID70501795

未命名化合物

PROCEDURE

实验过程

1.5 g of 11β,17,21-trihydroxy-6α-methyl-4-pregnene-3,20-dione is reacted analogously to Example 1(a) with methoxyacetic acid chloride, worked up, and chromatographed, thus isolating 1.6 g of 11β,17-dihydroxy-21-methoxyacetoxy-6α-methyl-4-pregnene-3,20-dione.

WORKUP

后处理

  1. customchromatographed