N-Allyl-2,2'-iminodiethanol → 2,2'-{[2-(2-Methoxyethoxy)ethyl]azanediyl}di(ethan-1-ol)

HRID 1903388Notes

Reaction equation

HRID 1903388 reaction equation
[CH2:1]([N:4]([CH2:8][CH2:9][OH:10])[CH2:5][CH2:6][OH:7])[CH:2]=C.S(C1C=CC(C)=CC=1)([O:14][CH2:15][CH2:16][O:17][CH2:18]COC)(=O)=O>>[CH3:18][O:17][CH2:16][CH2:15][O:14][CH2:2][CH2:1][N:4]([CH2:8][CH2:9][OH:10])[CH2:5][CH2:6][OH:7]

Participants

3

Reactant 2

HCID 41439N-Allyl-2,2'-iminodiethanolHCID 11076628HCID 11076628, compound

Product 1

HCID 136357232,2'-{[2-(2-Methoxyethoxy)ethyl]azanediyl}di(ethan-1-ol)

Procedure

The title compound was prepared as described above for N-allyldiethanolamine in Example 1 except that 2-methoxyethoxyethyl tosylate was used (0.55 mol, 150.9 g) in a 0.5 mol preparation. The pure diol whose formula is shown below was obtained (49.8 g, 48%) on fractional distillation at 129°-131° C. (0.04 mm):

Workup

  1. customin a 0.5 mol preparation
  2. custombelow was obtained (49.8 g, 48%)
  3. distillationon fractional distillation at 129°-131° C. (0.04 mm)

Sources & evidence

ORD record
ord-00593ba9d30d4b0892dcb3dd130175ef
Source dataset
uspto-grants-1984_03
Patent number
US04436664

Reaction notes

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