Benzoyl Peroxide → HCID 23438954, compound

HRID 1903711Notes

Reaction equation

HRID 1903711 reaction equation
[CH3:1][C:2]1[S:3][C:4]([C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=2)=[CH:5][CH:6]=1.[Br:13]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[Br:13][CH2:1][C:2]1[S:3][C:4]([C:7]2[CH:8]=[CH:9][CH:10]=[CH:11][CH:12]=2)=[CH:5][CH:6]=1

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 75788052-methyl-5-phenylthiophene

Product 1

HCID 23438954HCID 23438954, compound

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

To a boiling solution of 2-methyl-5-phenylthiophene (2g) in dry CCl4 (100 ml) was rapidly added N-bromosuccinimide (1.94 g) and dibenzoylperoxide (0.15 g). After heating under reflux for 30 min., the mixture was cooled and filtered. Evaporation in vacuo gave the title compound as an oil (1.5 g).

Workup

  1. temperatureAfter heating
  2. temperatureunder reflux for 30 min.
  3. temperaturethe mixture was cooled
  4. filtrationfiltered
  5. customEvaporation in vacuo

Sources & evidence

ORD record
ord-0902d85f48444f24ad68a2af63c4a5d5
Source dataset
uspto-grants-1984_03
Patent number
US04438111

Reaction notes

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