反应详情

A solution of 6,6-dimethyl-1-heptene (5.33 g, 0.0423 mol) and m-chloroperoxybenzoic acid (9.5 g of 85%, 0.048 mol) in dichloromethane (100 ml) was stirred at room temperature for 16 hours. The resulting solution was washed and aqueous sodium hydroxide (3×50 ml of 2M) and dried over sodium sulfate. The solvent was distilled off at atmospheric pressure to yield (4,4-dimethylpentyl)oxirane as a residue, having the following structural characteristics:

1. washThe resulting solution was washed
2. dry with materialaqueous sodium hydroxide (3×50 ml of 2M) and dried over sodium sulfate
3. distillationThe solvent was distilled off at atmospheric pressure