Dichloromethane → HCID 20039317, compound

HRID 1904515Notes

Reaction equation

HRID 1904515 reaction equation
[I-].[CH3:2][P+:3]([C:20]1[CH:25]=[CH:24][C:23]([C:26]([O:28][CH3:29])=[O:27])=[CH:22][CH:21]=1)([C:10]1[CH:15]=[CH:14][C:13]([C:16]([O:18][CH3:19])=[O:17])=[CH:12][CH:11]=1)[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.C(Cl)Cl.[C:33]1([B-:39]([C:52]2[CH:57]=[CH:56][CH:55]=[CH:54][CH:53]=2)([C:46]2[CH:51]=[CH:50][CH:49]=[CH:48][CH:47]=2)[C:40]2[CH:45]=[CH:44][CH:43]=[CH:42][CH:41]=2)[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=1.[Na+]>O>[C:52]1([B-:39]([C:33]2[CH:34]=[CH:35][CH:36]=[CH:37][CH:38]=2)([C:40]2[CH:41]=[CH:42][CH:43]=[CH:44][CH:45]=2)[C:46]2[CH:51]=[CH:50][CH:49]=[CH:48][CH:47]=2)[CH:53]=[CH:54][CH:55]=[CH:56][CH:57]=1.[CH3:2][P+:3]([C:10]1[CH:11]=[CH:12][C:13]([C:16]([O:18][CH3:19])=[O:17])=[CH:14][CH:15]=1)([C:20]1[CH:25]=[CH:24][C:23]([C:26]([O:28][CH3:29])=[O:27])=[CH:22][CH:21]=1)[C:4]1[CH:5]=[CH:6][CH:7]=[CH:8][CH:9]=1

Participants

5

Reactant 3

HCID 6344DichloromethaneHCID 2723787Sodium TetraphenylborateHCID 86743114HCID 86743114, compound

Product 1

HCID 20039317HCID 20039317, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A solution of 6.0 g (0.0115316 mol) of methylbis(4-carbomethoxyphenyl)phenylphosphonium iodide and 20 ml of methylene chloride was stirred rapidly with a solution of 3.95 g (0.0115316 mol) of sodium tetraphenylborate in 20 ml water for 2 hours. The organic layer was separated and washed with water, dried over magnesium sulfate, and concentrated.

Workup

  1. customThe organic layer was separated
  2. washwashed with water
  3. dry with materialdried over magnesium sulfate
  4. concentrationconcentrated

Sources & evidence

ORD record
ord-c4c7ae1370664a4d9c53f7455db53082
Source dataset
uspto-grants-1989_06
Patent number
US04837394

Reaction notes

Loading…