p-Toluenesulfonic acid → HCID 86743079, compound

HRID 1904802Notes

Reaction equation

HRID 1904802 reaction equation
[C:1]1([CH3:11])[CH:6]=[CH:5][C:4]([S:7]([OH:10])(=[O:9])=[O:8])=[CH:3][CH:2]=1.[C:12]([NH2:17])(=[O:16])[CH:13]1[O:15][CH2:14]1>CO.CCC(OC)O>[C:1]1([CH3:11])[CH:2]=[CH:3][C:4]([S:7]([OH:10])(=[O:8])=[O:9])=[CH:5][CH:6]=1.[C:12]([NH2:17])(=[O:16])[CH:13]1[O:15][CH2:14]1

Participants

5

Reactant 2

HCID 6101p-Toluenesulfonic acidHCID 91550Glycidamide

Product 1

HCID 86743079HCID 86743079, compound

Reagents, catalysts & solvents 2

HCID 887MethanolSolvent2×HCID 3032390Propylene glycol methyl etherSolvent

Procedure

122.9 parts by weight of a 70% p-toluenesulfonic acid solution supplied in Methanol by Jim Walters Resources is mixed with 282.6 parts by weight of methanol. This solution is then added to 167.5 parts by weight of a 26% glycidamide solution in Dowanol PM to give a homogeneous clear solution.

Workup

  1. customto give a homogeneous clear solution

Sources & evidence

ORD record
ord-9cea2ec5c8894b108d55f5d9379b36f1
Source dataset
uspto-grants-1989_06
Patent number
US04839427

Reaction notes

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