Aluminium lithium hydride → HCID 178463404, compound

HRID 1905938Notes

Reaction equation

HRID 1905938 reaction equation
[C:1]([NH:4][C:5]1[NH:6][CH:7]=[C:8]([C:10]2[CH:15]=[CH:14][C:13]([NH2:16])=[CH:12][CH:11]=2)[N:9]=1)(=O)[CH3:2].[H-].[Al+3].[Li+].[H-].[H-].[H-]>O1CCCC1>[CH2:1]([NH:4][C:5]1[NH:6][CH:7]=[C:8]([C:10]2[CH:15]=[CH:14][C:13]([NH2:16])=[CH:12][CH:11]=2)[N:9]=1)[CH3:2]

Participants

4

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 178474421HCID 178474421, compound

Product 1

HCID 178463404HCID 178463404, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent2×

Conditions

Temperature
60 °C

Procedure

A suspension of 2-acetamido-4-(4-amino-phenyl)-1H-imidazole (16 g) in anhydrous tetrahydrofuran (160 ml) was added dropwise to a stirred suspension of lithium aluminum hydride (12 g) in anhydrous tetrahydrofuran (240 ml). The mixture was heated at 60° C. for 4 hours.

Sources & evidence

ORD record
ord-bd185940d3bb432398707a42ec84aba0
Source dataset
uspto-grants-1987_03
Patent number
US04649150

Reaction notes

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