Sodium Chloride → Methyl alpha-iodophenylacetate

HRID 1906400Notes

Reaction equation

HRID 1906400 reaction equation
[I-:1].[Na+].Cl[CH:4]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:5]([O:7][CH3:8])=[O:6].[Cl-].[Na+]>CC(C)=O>[I:1][CH:4]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:5]([O:7][CH3:8])=[O:6]

Participants

5

Reactant 3

HCID 5234Sodium ChlorideHCID 5238Sodium IodideHCID 139032(+-)-Methyl alpha-chlorophenylacetate

Product 1

HCID 53848793Methyl alpha-iodophenylacetate

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

Sodium iodide (7.5 g, 0.05 mol) dissolved in analar acetone (25 ml) was stirred at room temperature and to it added methyl α-chlorophenylacetate (9.32 g, 0.05 mol). Stirred for 15 minutes. The precipitate sodium chloride was allowed to settle.

Workup

  1. stirringStirred for 15 minutes

Sources & evidence

ORD record
ord-048aec75fc0d43778bc0af414e8080ca
Source dataset
uspto-grants-1987_03
Patent number
US04652560

Reaction notes

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