Sodium aluminate → HCID 20332886, compound

HRID 1910319Notes

Reaction equation

HRID 1910319 reaction equation
[C:1]12([CH2:11][S:12]([OH:15])(=[O:14])=[O:13])[C:8]([CH3:10])([CH3:9])[CH:5]([CH2:6][CH2:7]1)[CH2:4][C:2]2=[O:3].O=[Al-:17]=O.[Na+]>>[C:1]12([CH2:11][S:12]([O-:15])(=[O:13])=[O:14])[C:8]([CH3:10])([CH3:9])[CH:5]([CH2:6][CH2:7]1)[CH2:4][C:2]2=[O:3].[Al+3:17].[C:1]12([CH2:11][S:12]([O-:15])(=[O:13])=[O:14])[C:8]([CH3:10])([CH3:9])[CH:5]([CH2:6][CH2:7]1)[CH2:4][C:2]2=[O:3].[C:1]12([CH2:11][S:12]([O-:15])(=[O:13])=[O:14])[C:8]([CH3:10])([CH3:9])[CH:5]([CH2:6][CH2:7]1)[CH2:4][C:2]2=[O:3]

Participants

3

Reactant 2

HCID 14766Sodium aluminateHCID 18462Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S)-

Product 1

HCID 20332886HCID 20332886, compound

Procedure

To the amine in the sodium aluminate example above, camphorsulfonic acid was added to bring the pH to the range of 7.5-9. The insoluble precipitate that formed was filtered before use. The control did not require any acid addition.

Workup

  1. customThe insoluble precipitate that formed
  2. filtrationwas filtered before use
  3. additionany acid addition

Sources & evidence

ORD record
ord-90bb52a396b3476ab0ea56d8443b0b34
Source dataset
uspto-grants-2013_12
Patent number
US08603340B2

Reaction notes

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