Tetrabutylammonium Fluoride → HCID 85561342, compound

HRID 1912029Notes

Reaction equation

HRID 1912029 reaction equation
[F:1]C(F)(F)C([O-])=O.[CH3:8][O:9][C:10]1[CH:15]=[CH:14][C:13]([I+:16][C:17]2[CH:22]=[CH:21][C:20]([O:23][CH3:24])=[CH:19][CH:18]=2)=[CH:12][CH:11]=1.CCCC[N+](CCCC)(CCCC)CCCC.[F-]>O1CCCC1>[F-:1].[CH3:24][O:23][C:20]1[CH:19]=[CH:18][C:17]([I+:16][C:13]2[CH:14]=[CH:15][C:10]([O:9][CH3:8])=[CH:11][CH:12]=2)=[CH:22][CH:21]=1

Participants

4

Reactant 2

HCID 2724141Tetrabutylammonium FluorideHCID 86652488HCID 86652488, compound

Product 1

HCID 85561342HCID 85561342, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

To a mixture of 454 mg (1 mmol) Bis(p-methoxyphenyl)iodonium trifluoroacetate and 262 mg (1 mmol) anhydrous TBAF was added 1 mL of dry tetrahydrofuran (THF). The solution was allowed to stand for 1 hour, the white precipitate was collected and washed with 3×0.5 mL THF.

Workup

  1. customthe white precipitate was collected
  2. washwashed with 3×0.5 mL THF

Sources & evidence

ORD record
ord-4112e7e4f6824502acec667dcf2fbb20
Source dataset
uspto-grants-2013_12
Patent number
US08604213B2

Reaction notes

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