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HRID1912746

反应详情

EQUATION

反应方程式

HRID 1912746 的结构方程式

REACTANTS

反应物

2
结构：Cl.NO
HCID443297

未命名化合物

结构：C[C@]12CC[C@H](SCCCCNC(=O)C(F)(F)F)CC1C(=O)C[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12
HCID86651522

未命名化合物

PRODUCTS

生成物

1
结构：C[C@]12CC[C@H](SCCCCNC(=O)C(F)(F)F)CC1/C(=N/O)C[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12
HCID87709821

未命名化合物

收率 40%

PROCEDURE

实验过程

Following the reaction conditions described in Example 1 and starting from 3β-(4-trifluoroacetamidobutylthio)androstane-6,17-dione and hydroxylamine hydrochloride, 3β-(4-trifluoroacetamidobutylthio)-6-(E)-hydroxyiminoandrostane-17-one (240 mg, 40%) was obtained. 1H-NMR (300 MHz, DMSO-d6, ppm from TMS): δ 10.35 (1H, s), 9.40 (1H, t), 3.20 (4H, m), 2.55-0.90 (25H, m), 0.76 (3H, s), 0.67 (3H, s).

WORKUP

后处理

  1. customthe reaction conditions