HuagongsheHuagongshe Chemistry Print Report · For research reference only
(+/-)-ethyl 2-(1-methyl-2,3-dihydro-1H-inden-1-yl)acetate → ethyl 2-(2,3-dihydro-1H-inden-1-yl)acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (+/-)-ethyl 2-(1-methyl-2,3-dihydro-1H-inden-1-yl)acetate | HCID 86665180 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | ethyl 2-(2,3-dihydro-1H-inden-1-yl)acetate | HCID 12322855 | 100% |
Reaction Steps
To a mixture of products from Example 131A (0.47 g, 2.3 mmol) in EtOH (20 mL) was added Pd/C (49.5 mg, 0.046 mmol). The reaction mixture was stirred under H2 atmosphere using a balloon until the starting material completely consumed. The mixture was filtered and concentrated under reduced pressure to obtain 0.47 g of the title compound. MS (DCI/NH3) m/z 222 (M+NH4)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08609669B2 |
| Source dataset | uspto-grants-2013_12 |
| ORD ID | ord-eed5562249a14ebfab76c882ef6eb241 |
| Source note | uspto-grants-2013_12 |