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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1912970Generated: October 31, 2026

(+/-)-ethyl 2-(1-methyl-2,3-dihydro-1H-inden-1-yl)acetate → ethyl 2-(2,3-dihydro-1H-inden-1-yl)acetate

https://huagongshe.com/reaction/1912970

Reaction equation

Participants

RoleNameHCIDCharge
Reactant(+/-)-ethyl 2-(1-methyl-2,3-dihydro-1H-inden-1-yl)acetateHCID 86665180—
CatalystPalladiumHCID 23938—
SolventEthanolHCID 702—
Productethyl 2-(2,3-dihydro-1H-inden-1-yl)acetateHCID 12322855100%

Reaction Steps

To a mixture of products from Example 131A (0.47 g, 2.3 mmol) in EtOH (20 mL) was added Pd/C (49.5 mg, 0.046 mmol). The reaction mixture was stirred under H2 atmosphere using a balloon until the starting material completely consumed. The mixture was filtered and concentrated under reduced pressure to obtain 0.47 g of the title compound. MS (DCI/NH3) m/z 222 (M+NH4)+.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS08609669B2
Source datasetuspto-grants-2013_12
ORD IDord-eed5562249a14ebfab76c882ef6eb241
Source noteuspto-grants-2013_12