Sulfuryl chloride → HCID 19067199, compound

HRID 1913540Notes

Reaction equation

HRID 1913540 reaction equation
[CH3:1][CH:2]([CH3:14])[C:3]([O:5][CH:6]([O:8][C:9](SCC)=[O:10])[CH3:7])=[O:4].S(Cl)([Cl:18])(=O)=O>>[CH3:1][CH:2]([CH3:14])[C:3]([O:5][CH:6]([O:8][C:9]([Cl:18])=[O:10])[CH3:7])=[O:4]

Participants

3

Reactant 2

HCID 24648Sulfuryl chlorideHCID 85885663HCID 85885663, compound

Product 1

HCID 19067199HCID 19067199, compound

Procedure

1-{[(Ethylthio)carbonyl]oxy}ethyl 2-methylpropionate (WO2005/66122) (412 mg) was cooled to −30° C. Sulfuryl chloride (157 μl) was added thereto, and the mixture was then stirred for 45 minutes. The solvent in the reaction solution was distilled off under reduced pressure to obtain a crude product of the title compound.

Workup

  1. distillationThe solvent in the reaction solution was distilled off under reduced pressure

Sources & evidence

ORD record
ord-4c9388d3f6914b59bd6bf7ca6ed00553
Source dataset
uspto-grants-2013_12
Patent number
US08609710B2

Reaction notes

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