Titanium tetrabutoxide → HCID 131731098, compound

HRID 1914966Notes

Reaction equation

HRID 1914966 reaction equation
[CH2:1]([P:3]([CH2:6][CH:7](C)[CH2:8][OH:9])(=[O:5])[OH:4])[CH3:2].[O-]CCCC.[O-]CCCC.[O-]CCCC.[O-]CCCC.[Ti+4:31]>C1(C)C=CC=CC=1>[Ti+4:31].[CH2:1]([P:3]([CH2:6][CH2:7][CH2:8][OH:9])(=[O:4])[O-:5])[CH3:2].[CH2:1]([P:3]([CH2:6][CH2:7][CH2:8][OH:9])(=[O:4])[O-:5])[CH3:2].[CH2:1]([P:3]([CH2:6][CH2:7][CH2:8][OH:9])(=[O:4])[O-:5])[CH3:2].[CH2:1]([P:3]([CH2:6][CH2:7][CH2:8][OH:9])(=[O:4])[O-:5])[CH3:2]

Participants

4

Reactant 2

HCID 21801Titanium tetrabutoxideHCID 46901656HCID 46901656, compound

Product 1

HCID 131731098HCID 131731098, compoundYield 98.8%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

166 g (1 mol) of ethyl(2-methyl-3-hydroxypropyl)phosphinic acid (produced as in Example 5) and 85 g of titanium tetrabutoxide are refluxed in 500 ml of toluene for 40 hours. The resulting butanol is distilled off from time to time with proportions of toluene. The solution formed is subsequently freed of solvent to leave 161 g (91% of theory) of ethyl(3-hydroxypropyl)phosphinic acid titanium salt.

Workup

  1. distillationThe resulting butanol is distilled off from time to time with proportions of toluene
  2. customThe solution formed

Sources & evidence

ORD record
ord-c1a50d46b5324158944b2c153da31777
Source dataset
uspto-grants-2013_12
Patent number
US08614267B2

Reaction notes

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