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HRID1915805

反应详情

EQUATION

反应方程式

HRID 1915805 的结构方程式

REACTANTS

反应物

2
结构：Cn1ncc([N+](=O)[O-])c1Br
HCID1279587

5-bromo-1-methyl-4-nitro-1H-pyrazole

C4H4BrN3O2

结构：CC(C)(C)OC(=O)N1CCNC(=O)CC1
HCID22617736

tert-Butyl 5-oxo-1,4-diazepane-1-carboxylate

C10H18N2O3

PRODUCTS

生成物

1
结构：Cn1ncc([N+](=O)[O-])c1N1CCN(C(=O)OC(C)(C)C)CCC1=O
HCID86680013

未命名化合物

收率 33%

PROCEDURE

实验过程

Following the procedure for Intermediate 202 starting from 5-bromo-1-methyl-4-nitro-1H-pyrazole and tert-butyl 5-oxo-1,4-diazepane-1-carboxylate gave tert-butyl 4-(1-methyl-4-nitro-1H-pyrazol-5-yl)-5-oxo-1,4-diazepane-1-carboxylate as a brown gum (136 mg, 33%). 1H NMR (400 MHz, d4-MeOD) δ 8.18 (s, 1H), 4.04-3.72 (m, 5H), 3.90-3.62 (m, 4H), 3.02-2.86 (m, 2H), 1.52 (s, 9H).