3-Chloro-2-methyl-1-propene → HCID 62001285, compound

HRID 1917012Notes

Reaction equation

HRID 1917012 reaction equation
[SH:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[OH:8].[CH2:9](Cl)[C:10](=[CH2:12])[CH3:11]>>[CH3:11][C:10](=[CH2:9])[CH2:12][S:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[OH:8]

Participants

3

Reactant 2

HCID 112413-Chloro-2-methyl-1-propeneHCID 70718Phenol, o-mercapto-(6CI,7CI,8CI)

Product 1

HCID 62001285HCID 62001285, compoundYield 65%

Procedure

This compound was prepared in 65% yield from 2-mercaptophenol and methallyl chloride according to the procedure for 16b in Example VII. Brown Oil; 1H NMR (CDCl3): δ 1.86 (s, 3H), 3.26 (s, 2H), 4.52 (s, 1H), 4.73 (s, 1H), 6.68 (s, 1H), 6.85 (dt, J=1.35 Hz, J=7.40 Hz, 1H), 6.97 (dd, J=1.1, J=8.0 Hz, 1H), 7.25 (dt, J=1.4, J=7.7, 1H), 7.39 (dd, J=1.7 Hz, J=7.7 Hz, 1H); 13C NMR (CDCl3): δ 20.91, 44.49, 114.74, 114.92, 118.84, 120.67, 131.25, 136.31, 140.32, 157.08.

Sources & evidence

ORD record
ord-2e5eb73bbeaf4b79b2ace83ae054dfdd
Source dataset
uspto-grants-2013_12
Patent number
US08618162B2

Reaction notes

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