HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Chloro-2-methyl-1-propene → HCID 62001285, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Chloro-2-methyl-1-propene | HCID 11241 | — |
| Reactant | Phenol, o-mercapto-(6CI,7CI,8CI) | HCID 70718 | — |
| Product | HCID 62001285 | HCID 62001285 | 65% |
Reaction Steps
This compound was prepared in 65% yield from 2-mercaptophenol and methallyl chloride according to the procedure for 16b in Example VII. Brown Oil; 1H NMR (CDCl3): δ 1.86 (s, 3H), 3.26 (s, 2H), 4.52 (s, 1H), 4.73 (s, 1H), 6.68 (s, 1H), 6.85 (dt, J=1.35 Hz, J=7.40 Hz, 1H), 6.97 (dd, J=1.1, J=8.0 Hz, 1H), 7.25 (dt, J=1.4, J=7.7, 1H), 7.39 (dd, J=1.7 Hz, J=7.7 Hz, 1H); 13C NMR (CDCl3): δ 20.91, 44.49, 114.74, 114.92, 118.84, 120.67, 131.25, 136.31, 140.32, 157.08.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08618162B2 |
| Source dataset | uspto-grants-2013_12 |
| ORD ID | ord-2e5eb73bbeaf4b79b2ace83ae054dfdd |
| Source note | uspto-grants-2013_12 |