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HRID1920311

反应详情

EQUATION

反应方程式

HRID 1920311 的结构方程式

REACTANTS

反应物

4
结构：Cl
HCID313

Hydrochloric Acid

ClH

结构：CC1(C)CCC(O)(c2ccc(Cl)cc2)/C(=C/O[Si](C)(C)C(C)(C)C)C1
HCID67079181

未命名化合物

结构：CC(C)[Si](O/C=C1\CC(C)(C)CCC1(O)c1ccc(Cl)cc1)(C(C)C)C(C)C
HCID67079716

未命名化合物

结构：CC1(C)CCC(O)(c2ccc(Cl)cc2)/C(=C/O[Si](C)(C)C)C1
HCID67079763

未命名化合物

PRODUCTS

生成物

1
结构：CC1(C)CCC(c2ccc(Cl)cc2)=C(C=O)C1
HCID44594330

未命名化合物

PROCEDURE

实验过程

reacting (2E)-1-(4-chlorophenyl)-4,4-dimethyl-2-(((triisopropylsilyl)oxy)methylene)cyclohexanol, (2E)-1-(4-chlorophenyl)-4,4-dimethyl-2-(((trimethylsilyl)oxy)methylene)cyclohexanol, or (2E)-2-(((tert-butyl(dimethyl)silyl)oxy)methylene)-1-(4-chlorophenyl)-4,4-dimethylcyclohexanol and hydrochloric acid to provide 2-(4-chlorophenyl)-5,5-dimethylcyclohex-1-ene-1-carbaldehyde and isolating or not isolating the 2-(4-chlorophenyl)-5,5-dimethylcyclohex-1-ene-1-carbaldehyde;