HRID1920335

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID313

Hydrochloric Acid

ClH

反应SMILES：CC1(C)CCC(O)(c2ccc(Cl)cc2)/C(=C/O[Si](C)(C)C(C)(C)C)C1

HCID67079181

未命名化合物

$反应SMILES：CC(C)[Si](O/C=C1\CC(C)(C)CCC1(O)c1ccc(Cl)cc1)(C(C)C)C(C)C$

HCID67079716

未命名化合物

反应SMILES：CC1(C)CCC(O)(c2ccc(Cl)cc2)/C(=C/O[Si](C)(C)C)C1

HCID67079763

未命名化合物

PRODUCTS

产物

反应SMILES：CC1(C)CCC(c2ccc(Cl)cc2)=C(C=O)C1

HCID44594330

未命名化合物

PROCEDURE

实验过程

reacting ((2E)-1-(4-chlorophenyl)-4,4-dimethyl-2-(((triisopropylsilyl)oxy)methylene)cyclohexanol, (2E)-1-(4-chlorophenyl)-4,4-dimethyl-2-(((trimethylsilyl)oxy)methylene)cyclohexanol, or (2E)-2-(((tert-butyl(dimethyl)silyl)oxy)methylene)-1-(4-chlorophenyl)-4,4-dimethylcyclohexanol and hydrochloric acid at about 5° C. to about 20° C. to provide 2-(4-chlorophenyl)-5,5-dimethylcyclohex-1-ene-1-carbaldehyde and isolating or not isolating the 2-(4-chlorophenyl)-5,5-dimethylcyclohex-1-ene-1-carbaldehyde.

WORKUP

后处理

customat about 5° C. to about 20° C.