Phosphorus pentachloride → HCID 59925880, compound

HRID 1925736Notes

Reaction equation

HRID 1925736 reaction equation
[C:1]([C:5]1[CH:10]=[CH:9][C:8]([S:11](O)(=[O:13])=[O:12])=[C:7]([F:15])[CH:6]=1)([CH3:4])([CH3:3])[CH3:2].C(C1C=C(F)C=CC=1S(O)(=O)=O)(C)(C)C.P(Cl)(Cl)(Cl)(Cl)[Cl:32]>ClC(Cl)C>[C:1]([C:5]1[CH:10]=[CH:9][C:8]([S:11]([Cl:32])(=[O:13])=[O:12])=[C:7]([F:15])[CH:6]=1)([CH3:4])([CH3:3])[CH3:2]

Participants

5

Reactant 3

HCID 24819Phosphorus pentachlorideHCID 59180449HCID 59180449, compoundHCID 86638763HCID 86638763, compound

Product 1

HCID 59925880HCID 59925880, compound

Reagents, catalysts & solvents 1

HCID 63651,1-DichloroethaneSolvent

Procedure

Synthesized as described for 2 using a 3:1 regioisomeric mixture of 107 (23.68 g; 0.10 mol) and 2-tert-butyl-4-fluorobenzenesulfonic acid, phosphorus pentachloride (23.13 g; 0.11 mol) and dichloroethane (700 mL). The title compound was obtained as a white solid which was a 1:1 regioisomeric ratio of itself and 2-tert-butyl-4-fluorobenzene-1-sulfonyl chloride (10.0 g).

Workup

  1. customSynthesized

Sources & evidence

ORD record
ord-e9c3485f2f764b52b48fc9d00d11dd23
Source dataset
uspto-grants-2012_05
Patent number
US08178699B2

Reaction notes

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