HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,2-Cyclopentanedicarboxylic acid, 3-oxo-, 1,2-dimethyl ester → HCID 10878160, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,2-Cyclopentanedicarboxylic acid, 3-oxo-, 1,2-dimethyl ester | HCID 13323859 | — |
| Reactant | HCID 18738774 | HCID 18738774 | — |
| Reactant | HCID 18738795 | HCID 18738795 | — |
| Product | HCID 10878160 | HCID 10878160 | — |
Reaction Steps
2,4-Bis(methoxycarbonyl)cyclopentanone (Compound 1A-A) is prepared as a mixture with 2,3-bis(methoxycarbonyl)cyclopentanone (Compound 1-Aa), e.g., by the process described in J. Org. Chem., 47, 2379 (1982). By converting the mixture into 2,4-bis(hydroxymethyl)cyclopentanone and 2,3-bis(hydroxymethyl)cyclopentanone, the two compounds can be separated from each other by silica gel column chromatography.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06384063B1 |
| Source dataset | uspto-grants-2002_05 |
| ORD ID | ord-2912e89d10264af2b94bf0e61ffac773 |
| Source note | uspto-grants-2002_05 |