HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1935313Generated: October 30, 2026
Hydrochloric Acid → 2,3-Di(9-(Z)-octadecenyl)propan-1ol
https://huagongshe.com/reaction/1935313
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Sodium borohydride | HCID 4311764 | — |
| Reactant | 2,3-di(9-(Z)-octadecenyl)propanal | HCID 86743718 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Solvent | MeOH tetrahydrofuran | HCID 21899815 | — |
| Product | 2,3-Di(9-(Z)-octadecenyl)propan-1ol | HCID 86743717 | — |
Reaction Steps
Crude 2,3-di(9-(Z)-octadecenyl)propanal of formula (10) from Preparation 7 (10.0 g, 16.9 mmol) was dissolved in tetrahydrofuran/methanol (1:1, 200 ml) and cooled to 0° C. Sodium borohydride (3.13 g, 85.0 mmol) was added and the mixture was stirred overnight. The solution was acidified with 1N HCl to pH<2, diluted with ether, washed with water, concentrated and column chromatographed (chloroform) to give the title compound as an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US06387395B1 |
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| Source dataset | uspto-grants-2002_05 |
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| ORD ID | ord-22b98520e48541279ae004e3a7ee1668 |
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| Source note | uspto-grants-2002_05 |
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