Oxygen → HCID 12039381, compound

HRID 1936530Notes

Reaction equation

HRID 1936530 reaction equation
[C:1]([O:5][C:6]([C:8]12[CH2:17][CH:12]3[CH2:13][CH:14]([CH2:16][C:10]([C:18]([O:20][C:21]([CH3:24])([CH3:23])[CH3:22])=[O:19])([CH2:11]3)[CH2:9]1)[CH2:15]2)=[O:7])([CH3:4])([CH3:3])[CH3:2].[O:25]=O>C(O)(=O)C>[C:21]([O:20][C:18]([C:10]12[CH2:16][C:14]3([OH:25])[CH2:13][CH:12]([CH2:17][C:8]([C:6]([O:5][C:1]([CH3:4])([CH3:3])[CH3:2])=[O:7])([CH2:15]3)[CH2:9]1)[CH2:11]2)=[O:19])([CH3:24])([CH3:23])[CH3:22]

Participants

4

Reactant 2

HCID 977OxygenHCID 11209898HCID 11209898, compound

Product 1

HCID 12039381HCID 12039381, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

A mixture of 10 mmol of the obtained 1.3-di(t-butoxycarbonyl)adamantane, 2 mmol of NHPI, 0.1 mmol of acetylacetonatocobalt Co(AA)2, and 25 ml of acetic acid was stirred in an atmosphere of oxygen at 75° C. for 6 hours. As a result, there was obtained 1,3-di(t-butoxycarbonyl)-5-hydroxyadamantane.

Sources & evidence

ORD record
ord-803503d2d2e6434088936d9325d3e78d
Source dataset
uspto-grants-2002_05
Patent number
US06391520B1

Reaction notes

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