Magnesium → HCID 22462462, compound

HRID 1936996Notes

Reaction equation

HRID 1936996 reaction equation
[CH3:1][C:2]1[CH:11]=[CH:10][C:9]2[NH:8][C:7](=[O:12])[C:6]3[CH2:13][CH2:14][CH2:15][C:5]=3[C:4]=2[CH:3]=1.[Mg]>>[CH3:1][C:2]1[CH:11]=[CH:10][C:9]2[NH:8][C:7](=[O:12])[CH:6]3[CH2:13][CH2:14][CH2:15][CH:5]3[C:4]=2[CH:3]=1

Participants

3

Reactant 2

HCID 5462224MagnesiumHCID 22462487HCID 22462487, compound

Product 1

HCID 22462462HCID 22462462, compound

Procedure

8-Methyl-1,2,3,5-tetrahydrocyclopenta[c]quinolin-4-one (R. J. Brown, F. W. S. Carver, B. L. Hollingsworth, J. Chem. Soc. 1961, 4295) (1.20 g, 6.0 mmol) and magnesium (1.46 g, 60 mmol) are converted into 0.48 g (40%) of product analogously to Example 7.

Sources & evidence

ORD record
ord-b2c2407e91194ad5ba28c25d6997c59f
Source dataset
uspto-grants-2002_05
Patent number
US06391887B1

Reaction notes

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