HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl Chloride → Benzene, [(trichlorosilyl)methyl]-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl Chloride | HCID 7503 | — |
| Reactant | Trichlorosilane | HCID 24811 | — |
| Reactant | Benzyltributylphosphonium chloride | HCID 200231 | — |
| Product | Benzene, [(trichlorosilyl)methyl]- | HCID 69863 | 802.5% |
Reaction Steps
In the same apparatus and procedure as Example 1 above, 0.26 g (0.79 mmol) of benzyltributylphosphonium chloride, 1.00 g (7.90 mmol) of benzyl chloride, and 3.21 g (23.7 mmol) of trichlorosilane were reacted at 150° C. for 2 hrs. The resulting mixture was distilled to give 1.43 g of benzyltrichlorosilane (yield; 80%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06392077B1 |
| Source dataset | uspto-grants-2002_05 |
| ORD ID | ord-debc401b5c524fd78cb7b8c62d241c7c |
| Source note | uspto-grants-2002_05 |