HRID1937211

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID5948

Tributyltin

C12H28Sn

HCID8900

Heptane

C7H16

HCID12225

Ethanol, 2-iodo-

C2H5IO

结构：CC1(C)CC(OC(=O)CCCCCCCCC(=O)OC2CC(C)(C)N(O)C(C)(C)C2)CC(C)(C)N1O

HCID11272241

Bis-(tetramethyl hydroxypiperidinyl) sebacate

C28H52N2O6

HCID21899848

未命名化合物

PRODUCTS

生成物

结构：CC1(C)CC(OC(=O)CCCCCCCCC(=O)OC2CC(C)(C)N(OCCO)C(C)(C)C2)CC(C)(C)N1OCCO

HCID22507665

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID7964

Chlorobenzene

C6H5Cl

PROCEDURE

实验过程

Tributyltin hydride is added dropwise to a solution of 2-iodoethanol and excess bis(1-oxyl-—2,2,6,6-tetramethylpiperidin-4-yl) sebacate in chlorobenzene. The crude reaction mixture is passed through silica gel with heptane and then heptane/ethyl acetate to afford the title compound.

WORKUP

后处理

customThe crude reaction mixture

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-daa7967ca0754549bd483ed734b33953
来源数据集: uspto-grants-2002_05
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06391949B1
来源说明: uspto-grants-2002_05

反应 SMILES

C([SnH](CCCC)CCCC)CCC.I[CH2:15][CH2:16][OH:17].[C:18]([O:42][CH:43]1[CH2:48][C:47]([CH3:50])([CH3:49])[N:46]([OH:51])[C:45]([CH3:53])([CH3:52])[CH2:44]1)(=[O:41])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][C:27]([O:29][CH:30]1[CH2:35][C:34]([CH3:37])([CH3:36])[N:33]([OH:38])[C:32]([CH3:40])([CH3:39])[CH2:31]1)=[O:28].CCCCCCC.CCCCCCC.[C:68](OCC)(=[O:70])[CH3:69]>ClC1C=CC=CC=1>[C:18]([O:42][CH:43]1[CH2:44][C:45]([CH3:53])([CH3:52])[N:46]([O:51][CH2:69][CH2:68][OH:70])[C:47]([CH3:50])([CH3:49])[CH2:48]1)(=[O:41])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][C:27]([O:29][CH:30]1[CH2:31][C:32]([CH3:39])([CH3:40])[N:33]([O:38][CH2:15][CH2:16][OH:17])[C:34]([CH3:36])([CH3:37])[CH2:35]1)=[O:28]