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Benzoyl Peroxide → (3-(Bromomethyl)phenyl)trimethylsilane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzoyl Peroxide | HCID 7187 | — |
| 反応物 | N-bromobutanimide | HCID 67184 | — |
| 反応物 | Trimethyl(M-tolyl)silane | HCID 10866684 | — |
| 溶媒 | Carbon Tetrachloride | HCID 5943 | — |
| 生成物 | (3-(Bromomethyl)phenyl)trimethylsilane | HCID 12583977 | — |
反応手順
A mixture of 3-trimethylsilyltoluene (3.28 g, 10 mmol), N-bromosuccinimide (1.78 g, 10 mmol) and benzoylperoxide (10 mg) in CCl4 (20 ml) was stirred under reflux for 3 hours, then cooled and filtered. The solvent was removed under reduced pressure and 3-trimethylsilylbenzylbromide was purified by distillation.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05693668 |
| 出典データセット | uspto-grants-1997_12 |
| ORD ID | ord-51497a61883e44c8b841f8ccf3198710 |
| 出典メモ | uspto-grants-1997_12 |