4-Nitrophenol → Methyl (4-nitrophenoxy)acetate

HRID 1940520Notes

Reaction equation

[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([OH:10])=[CH:6][CH:5]=1)([O-:3])=[O:2].[CH3:11][O:12][C:13](=[O:16])[CH2:14]Br.C(=O)([O-])[O-].[Cs+].[Cs+]>>[CH3:11][O:12][C:13]([CH2:14][O:10][C:7]1[CH:8]=[CH:9][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][CH:6]=1)=[O:16]

Participants

Reactant 3

HCID 9804-Nitrophenol

HCID 10796Cesium carbonate

HCID 60984Methyl bromoacetate

Product 1

HCID 700522Methyl (4-nitrophenoxy)acetate

Procedure

Prepared from 4-nitrophenol, methylbromoacetate and caesium carbonate analogously to Example XIXa.

Sources & evidence

ORD record: ord-80a554dd3da545d8892e1a2074c2f513
Source dataset: uspto-grants-1997_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05700801

Reaction notes

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