Pentane → HCID 131720369, compound

HRID 1941434Notes

Reaction equation

HRID 1941434 reaction equation
[CH3:1][C:2]1[C:3]([CH3:21])=[C:4]([CH3:20])[C:5]([Si:8]([NH:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=2[O:18][CH3:19])([CH3:10])[CH3:9])([CH3:7])[CH:6]=1.C([Li:26])CCC.CCCCC>C(OCC)C.CCCCCC>[CH3:1][C:2]1[C:3]([CH3:21])=[C:4]([CH3:20])[C:5]([Si:8]([N-:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=2[O:18][CH3:19])([CH3:10])[CH3:9])([CH3:7])[CH:6]=1.[Li+:26].[Li+:26].[CH3:1][C:2]1[C:3]([CH3:21])=[C:4]([CH3:20])[C:5]([Si:8]([N-:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=2[O:18][CH3:19])([CH3:10])[CH3:9])([CH3:7])[CH:6]=1

Participants

6

Reactant 3

HCID 8003PentaneHCID 131720370HCID 131720370, compoundHCID 178418339Butyllithium

Product 1

HCID 131720369HCID 131720369, compound

Reagents, catalysts & solvents 2

HCID 3283Diethyl EtherSolventHCID 8058HexaneSolvent

Procedure

To 1.4 g (4.6 mmol) ((tetramethylcyclopentadienyl) dimethylsilyl)(2-methoxyphenyl)amine in diethyl ether was added dropwise 3.9 mL of 2.5M butyl lithium (9.8 mmol) in hexane solvent. A white precipitate formed. Pentane was added to the mixture. The slurry was filtered and the solids washed with pentane.

Workup

  1. customA white precipitate formed
  2. filtrationThe slurry was filtered
  3. washthe solids washed with pentane

Sources & evidence

ORD record
ord-707ffc81f0464af4b1aefc09d2cbb414
Source dataset
uspto-grants-1997_12
Patent number
US05703187

Reaction notes

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