Potassium Nitrate → HCID 58346346, compound

HRID 1941768Notes

Reaction equation

HRID 1941768 reaction equation
[F:1][C:2]1[CH:3]=[C:4]2[C:9]3=[C:10]([O:13][CH2:14][C:15]([CH3:17])([CH3:16])[N:8]3[CH:7]=[C:6]([C:18]([OH:20])=[O:19])[C:5]2=[O:21])[C:11]=1[F:12].[N+:22]([O-])([O-:24])=[O:23].[K+]>OS(O)(=O)=O>[F:1][C:2]1[C:3]([N+:22]([O-:24])=[O:23])=[C:4]2[C:9]3=[C:10]([O:13][CH2:14][C:15]([CH3:17])([CH3:16])[N:8]3[CH:7]=[C:6]([C:18]([OH:20])=[O:19])[C:5]2=[O:21])[C:11]=1[F:12]

Participants

4

Reactant 2

HCID 24434Potassium NitrateHCID 13747366HCID 13747366, compound

Product 1

HCID 58346346HCID 58346346, compoundYield 87.9%

Reagents, catalysts & solvents 1

HCID 1118Sulfuric AcidSolvent

Conditions

Temperature
0 °C

Procedure

A solution of 8 (7.5 g, 25.4 mmol) in concentrated H2SO4 (30 mL) was treated portionwise at 0° C. with solid KNO3 (3.9 g, 38.6 mmol). After stirring at 0° C. for 2 h, the reaction mixture was poured into 500 mL of ice-water and the resulting precipitate was removed by filtration and washed with ice-cold water. The resulting solid was dried to yield 9 as a yellow solid (7.6 g, 87% yield).

Workup

  1. customthe resulting precipitate was removed by filtration
  2. washwashed with ice-cold water
  3. customThe resulting solid was dried

Sources & evidence

ORD record
ord-61b9eae2e216421a8218e6a57e054dd4
Source dataset
uspto-grants-2013_03
Patent number
US08389514B2

Reaction notes

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