HCID 46872055, compound → HCID 46872057, compound

HRID 1943583Notes

Reaction equation

FC(F)(OC1C=CC(N=NC2C=CC(N)=CC=2)=CC=1)[C:3]([F:6])([F:5])[F:4].[CH2:24]([O:26][C@@H:27]1[C@@H:32]([O:33][CH3:34])[C@H:31]([CH3:35])[O:30][C@@H:29]([O:36][C:37](=[O:61])[NH:38][C:39]2[CH:44]=[CH:43][C:42]([N:45]=[N:46][C:47]3[CH:52]=[CH:51][C:50]([O:53]C(F)(F)C(F)(F)F)=[CH:49][CH:48]=3)=[CH:41][CH:40]=2)[C@@H:28]1[O:62][CH3:63])[CH3:25]>>[CH2:24]([O:26][C@@H:27]1[C@@H:32]([O:33][CH3:34])[C@H:31]([CH3:35])[O:30][C@@H:29]([O:36][C:37](=[O:61])[NH:38][C:39]2[CH:44]=[CH:43][C:42]([N:45]=[N:46][C:47]3[CH:52]=[CH:51][C:50]([O:53][C:3]([F:6])([F:5])[F:4])=[CH:49][CH:48]=3)=[CH:41][CH:40]=2)[C@@H:28]1[O:62][CH3:63])[CH3:25]

Participants

Reactant 2

HCID 46872055HCID 46872055, compound

HCID 87562317HCID 87562317, compound

Product 1

HCID 46872057HCID 46872057, compound

Procedure

4-(4-Pentafluoroethoxyphenylazo)aniline 1H NMR (300 MHz, CDCl3) δ7.89-7.79 (m, 4H), 7.32 (d, J=8.5 Hz, 2H), 6.73-6.76 (m, 2H), 4.09 (br s, 2H); ESIMS m/z 332 ([M+H]+). Step 2. Compound 22. 1H NMR (300 MHz, CDCl3) δ 7.96-7.92 (m, 4H), 7.60-7.57 (m, 2H), 7.38-7.35 (m, 2H), 6.86 (s, 1H), 6.26 (s, 1H), 3.75-3.45 (m, 11H), 3.22 (t, J=9.3 Hz, 1H), 1.33-1.26 (m, 6H); ESIMS m/z 578 ([M+H]+).

Sources & evidence

ORD record: ord-6607815566a641ee990f2d8cc5aa16ed
Source dataset: uspto-grants-2013_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08394774B2

Reaction notes

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