HRID1944925

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID20071424

1-{4-[(6-Bromohexyl)oxy]butyl}-4-nitrobenzene

C16H24BrNO3

结构：CN(CCCC#Cc1ccc(NC(=O)C(F)(F)F)cc1)C[C@H](O[Si](C)(C)C(C)(C)C)c1ccc(O)c2[nH]c(=O)ccc12

HCID58505093

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)[Si](C)(C)O[C@@H](CNCCCCCCOCCCCc1ccc([N+](=O)[O-])cc1)c1ccc(O)c2[nH]c(=O)ccc12

HCID58505188

未命名化合物

PROCEDURE

实验过程

The title compound was synthesized in a manner analogous to that described for Intermediate 102, using Intermediate 52 in place of Intermediate 45. ES/MS calcd. for C33H50N3O6Si+ 612.4. Found m/z=612.5 (M+H)+.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-51a38937c26340a3bfc8825a142d9f3c
来源数据集: uspto-grants-2013_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08394829B2
来源说明: uspto-grants-2013_03

反应 SMILES

[Si:1]([O:8][C@H:9]([C:31]1[CH:40]=[CH:39][C:38]([OH:41])=[C:37]2[C:32]=1[CH:33]=[CH:34][C:35](=[O:42])[NH:36]2)[CH2:10][N:11]([CH3:30])CCCC#CC1C=CC(NC(=O)C(F)(F)F)=CC=1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2].BrC[CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][O:50][CH2:51][CH2:52][CH2:53][CH2:54][C:55]1[CH:60]=[CH:59][C:58]([N+:61]([O-:63])=[O:62])=[CH:57][CH:56]=1>>[OH:41][C:38]1[CH:39]=[CH:40][C:31]([C@H:9]([CH2:10][NH:11][CH2:30][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][O:50][CH2:51][CH2:52][CH2:53][CH2:54][C:55]2[CH:60]=[CH:59][C:58]([N+:61]([O-:63])=[O:62])=[CH:57][CH:56]=2)[O:8][Si:1]([CH3:3])([CH3:2])[C:4]([CH3:6])([CH3:7])[CH3:5])=[C:32]2[C:37]=1[NH:36][C:35](=[O:42])[CH:34]=[CH:33]2