HRID1944927

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID13592784

未命名化合物

结构：CC(C)(C)[Si](C)(C)O[C@@H](CNCCCCCCOCCCCc1ccc([N+](=O)[O-])cc1)c1ccc(O)c2[nH]c(=O)ccc12

HCID58505188

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)[Si](C)(C)O[C@@H](CNCCCCCCOCCc1ccc([N+](=O)[O-])cc1)c1ccc(O)c2[nH]c(=O)ccc12

HCID58505219

未命名化合物

PROCEDURE

实验过程

The title compound was synthesized in a manner analogous to that described for Intermediate 106, using Intermediate 53 in place of Intermediate 52. ES/MS calcd. for C31H46N3O6Si+ 584.3. Found m/z=584.4 (M+H)+.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b67de987fe1f4c61ad46c14e1d3a1d20
来源数据集: uspto-grants-2013_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08394829B2
来源说明: uspto-grants-2013_03

反应 SMILES

[OH:1][C:2]1[CH:3]=[CH:4][C:5]([C@H:13]([CH2:22][NH:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][O:30][CH2:31]CCCC2C=CC([N+]([O-])=O)=CC=2)[O:14][Si:15]([CH3:21])([CH3:20])[C:16]([CH3:19])([CH3:18])[CH3:17])=[C:6]2[C:11]=1[NH:10][C:9](=[O:12])[CH:8]=[CH:7]2.BrCCCCCCOC[CH2:53][C:54]1[CH:59]=[CH:58][C:57]([N+:60]([O-:62])=[O:61])=[CH:56][CH:55]=1>>[OH:1][C:2]1[CH:3]=[CH:4][C:5]([C@H:13]([CH2:22][NH:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][O:30][CH2:31][CH2:53][C:54]2[CH:59]=[CH:58][C:57]([N+:60]([O-:62])=[O:61])=[CH:56][CH:55]=2)[O:14][Si:15]([CH3:20])([CH3:21])[C:16]([CH3:17])([CH3:19])[CH3:18])=[C:6]2[C:11]=1[NH:10][C:9](=[O:12])[CH:8]=[CH:7]2