HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Bromo-2-nitrobenzene → 7-Methoxy-3-(2-nitrophenyl)-1,2-dihydronaphthalene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Bromo-2-nitrobenzene | HCID 11341 | — |
| Reactant | Stannane, tributyl(2-nitrophenyl)- | HCID 11338886 | — |
| Reactant | 6-Methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonate | HCID 15330256 | — |
| Product | 7-Methoxy-3-(2-nitrophenyl)-1,2-dihydronaphthalene | HCID 23087148 | — |
Reaction Steps
Synthesized from 1-bromo-2-nitrobenzene according to an analogous synthetic method to Preparation Example 76, tributyl(2-nitrophenyl)tin (7.3 g) and 6-methoxy-3,4-dihydronaphthalen-2-yl trifluoromethanesulfonate (2.2 g) were used according to an analogous synthetic method to Preparation Example 77 to provide the title compound (1.5 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08399520B2 |
| Source dataset | uspto-grants-2013_03 |
| ORD ID | ord-076b8ff06e8643a09f2a5fa280dc557f |
| Source note | uspto-grants-2013_03 |