N,N,N',N'-Tetramethylethylenediamine → HCID 68553342, compound

HRID 1950696Notes

Reaction equation

HRID 1950696 reaction equation
Br[CH:2]([CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])[CH2:3][CH2:4][CH2:5][CH2:6][CH3:7].CN(C)CCN(C)C.[CH3:25][O:26][C:27]1[CH:32]=[CH:31][C:30]([Mg]Br)=[CH:29][CH:28]=1>C1COCC1>[CH3:25][O:26][C:27]1[CH:32]=[CH:31][C:30]([CH:2]([CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])[CH2:3][CH2:4][CH2:5][CH2:6][CH3:7])=[CH:29][CH:28]=1

Participants

5

Reactant 3

HCID 8037N,N,N',N'-TetramethylethylenediamineHCID 866397806-Bromo-pentadecaneHCID 178491912HCID 178491912, compound

Product 1

HCID 68553342HCID 68553342, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

The title compound (34.8 g) was prepared from 6-bromo-pentadecane (Example 12, 34 g), N,N,N′,N′-tetramethyletane-1,2-diamine (14.92 g), THF (35 ml) and (4-methoxyphenyl)magnesium bromide (0.5M in THF, 226.5 ml) using the procedure of Example 7.

Sources & evidence

ORD record
ord-2ea626b0904b488991bf5f83c641f101
Source dataset
uspto-grants-2013_03
Patent number
US08404627B2

Reaction notes

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