HRID1952273

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID11829503

6,6-Dimethyl-1-Vinylcyclohexene

C10H16

HCID46911800

2-[(Prop-2-en-1-yl)oxy]cyclohexa-2,5-diene-1,4-dione

C9H8O3

PRODUCTS

产物

反应SMILES：C=CCOC1=CC(=O)c2ccc3c(c2C1=O)CCCC3(C)C

HCID68601845

未命名化合物

收率 36%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

2-Allyloxy-1,4-benzoquinone (10.0 g, 60.9 mM) and 6,6-Dimethyl-1-Vinylcyclohexene (19.8 g, 183 mM) were dissolved in 100 ml of MeOH, and refluxed for 3 hours. 3-Allyloxy-8,8-dimethyl-5,6,7,8-tetrahydro-1,4-phenanthrenequinone (6.5 g, 22.0 mM) was obtained in the same manner as in Example 1.

WORKUP

后处理

temperaturerefluxed for 3 hours