Vinylcyclohexene → HCID 68600744, compound

HRID 1952274Notes

Reaction equation

HRID 1952274 reaction equation
[CH2:1]([O:6][C:7]1[C:8](=[O:14])[CH:9]=[CH:10][C:11](=[O:13])[CH:12]=1)[CH:2]=[C:3]([CH3:5])[CH3:4].[CH:15]([C:17]1[CH2:22][CH2:21][CH2:20][CH2:19][CH:18]=1)=[CH2:16]>CO>[CH2:1]([O:6][C:7]1[C:8](=[O:14])[C:9]2[C:10](=[CH:16][CH:15]=[C:17]3[C:18]=2[CH2:19][CH2:20][CH2:21][CH2:22]3)[C:11](=[O:13])[CH:12]=1)[CH:2]=[C:3]([CH3:5])[CH3:4]

Participants

4

Reactant 2

HCID 17497VinylcyclohexeneHCID 534204902,5-Cyclohexadiene-1,4-dione, 2-[(3-methyl-2-buten-1-yl)oxy]-

Product 1

HCID 68600744HCID 68600744, compoundYield 34.8%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

2-Prenyloxy-1,4-benzoquinone (3.0 g, 15.6 mM) and 1-Vinylcyclohexene (6.75 g, 62.5 mM) were dissolved in 50 ml of MeOH, and refluxed for 3 hours. 3-Prenyloxy-5,6,7,8-tetrahydro-1,4-phenanthrenequinone (1.61 g, 5.44 mM) was obtained in the same manner as in Example 1.

Workup

  1. temperaturerefluxed for 3 hours

Sources & evidence

ORD record
ord-1a65e1b4bd5a4cd6927492f51e8c2072
Source dataset
uspto-grants-2013_03
Patent number
US08404869B2

Reaction notes

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