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HRID1952275

反应详情

EQUATION

反应方程式

HRID 1952275 的结构方程式

REACTANTS

反应物

2
反应SMILES：C=CC1=CCCCC1(C)C
HCID11829503

6,6-Dimethyl-1-Vinylcyclohexene

C10H16

反应SMILES：CC(C)=CCOC1=CC(=O)C=CC1=O
HCID53420490

2,5-Cyclohexadiene-1,4-dione, 2-[(3-methyl-2-buten-1-yl)oxy]-

C11H12O3

PRODUCTS

产物

1
反应SMILES：CC(C)=CCOC1=CC(=O)c2ccc3c(c2C1=O)CCCC3(C)C
HCID68599654

未命名化合物

收率 35.5%

AUXILIARIES

试剂、催化剂与溶剂

1
反应SMILES：CO
溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

2-Prenyloxy-1,4-benzoquinone (20.0 g, 0.104 M) and 6,6-Dimethyl-1-vinylcyclohexene (56.7 g, 0.416 M) were dissolved in 150 ml of MeOH, and refluxed for 3 hours. 3-Prenyloxy-8,8-dimethyl-5,6,7,8-tetrahydro-1,4-phenanthrenequinone (12.0 g, 0.037 M) was obtained in the same manner as in Example 1.

WORKUP

后处理

  1. temperaturerefluxed for 3 hours