Isopropanol → HCID 178439733, compound

HRID 1952278Notes

Reaction equation

C([O:4][C:5]1[C:6](=[O:12])[CH:7]=[CH:8][C:9](=[O:11])[CH:10]=1)C=C.[CH3:13][C:14]([C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)=[CH2:15].[CH:22](O)([CH3:24])[CH3:23]>>[CH2:24]([C:10]1[C:9](=[O:11])[C:8]2[CH:15]=[C:14]([CH3:13])[C:16]3[C:21]([C:7]=2[C:6](=[O:12])[C:5]=1[OH:4])=[CH:20][CH:19]=[CH:18][CH:17]=3)[CH:22]=[CH2:23]

Participants

Reactant 3

HCID 3776Isopropanol

HCID 7407Alpha-Methylstyrene

HCID 469118002-[(Prop-2-en-1-yl)oxy]cyclohexa-2,5-diene-1,4-dione

Product 1

HCID 178439733HCID 178439733, compound

Procedure

2-Allyloxy-1,4-benzoquinone (10.0 g, 61 mM) and α-Methylstyrene (70 g, 0.59 M) were dissolved in 120 ml of isopropanol to give 3.6 g (14 mM) of 2-Allyl-3-hydroxy-9-methyl-1,4-phenanthrenequinone in the same manner as in Example 7.

Sources & evidence

ORD record: ord-6a39d0cdb6af41388609868f3b9f9496
Source dataset: uspto-grants-2013_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08404869B2

Reaction notes

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