Isopropanol → HCID 178439728, compound

HRID 1952279Notes

Reaction equation

C([O:4][C:5]1[C:6](=[O:12])[CH:7]=[CH:8][C:9](=[O:11])[CH:10]=1)C=C.[C:13]([C:17]1[CH:24]=[CH:23][C:20]([CH:21]=[CH2:22])=[CH:19][CH:18]=1)([CH3:16])([CH3:15])[CH3:14].[CH:25](O)([CH3:27])[CH3:26]>>[CH2:27]([C:10]1[C:9](=[O:11])[C:8]2[CH:22]=[CH:21][C:20]3[C:19]([C:7]=2[C:6](=[O:12])[C:5]=1[OH:4])=[CH:18][C:17]([C:13]([CH3:16])([CH3:14])[CH3:15])=[CH:24][CH:23]=3)[CH:25]=[CH2:26]

Participants

Reactant 3

HCID 3776Isopropanol

HCID 156274-tert-Butylstyrene

HCID 469118002-[(Prop-2-en-1-yl)oxy]cyclohexa-2,5-diene-1,4-dione

Product 1

HCID 178439728HCID 178439728, compound

Procedure

2-Allyloxy-1,4-benzoquinone (6.56 g, 40 mM) and p-tert-Butylstyrene (70 g, 0.40 M) were dissolved in 80 ml of isopropanol to give 1.90 g (5.9 mM) of 2-Allyl-3-hydroxy-6-tert-butyl-1,4-phenanthrenequinone in the same manner as in Example 7.

Sources & evidence

ORD record: ord-9eb011c7f79942c29fa69dad3c3b1a42
Source dataset: uspto-grants-2013_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08404869B2

Reaction notes

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