Isopropanol → HCID 178439729, compound

HRID 1952280Notes

Reaction equation

C([O:4][C:5]1[C:6](=[O:12])[CH:7]=[CH:8][C:9](=[O:11])[CH:10]=1)C=C.[Cl:13][C:14]1[CH:21]=[CH:20][C:17]([CH:18]=[CH2:19])=[CH:16][CH:15]=1.[CH:22](O)([CH3:24])[CH3:23]>>[CH2:24]([C:10]1[C:9](=[O:11])[C:8]2[CH:19]=[CH:18][C:17]3[C:20]([C:7]=2[C:6](=[O:12])[C:5]=1[OH:4])=[CH:21][C:14]([Cl:13])=[CH:15][CH:16]=3)[CH:22]=[CH2:23]

Participants

Reactant 3

HCID 3776Isopropanol

HCID 140854-Chlorostyrene

HCID 469118002-[(Prop-2-en-1-yl)oxy]cyclohexa-2,5-diene-1,4-dione

Product 1

HCID 178439729HCID 178439729, compound

Procedure

2-Allyloxy-1,4-benzoquinone (6.56 g, 40 mM) and p-Chlorostyrene (60 g, 0.44 M) were dissolved in 80 ml of isopropanol to give 0.74 g (2.48 mM) of 2-Allyl-3-hydroxy-6-chloro-1,4-phenanthrenequinone in the same manner as in Example 7.

Sources & evidence

ORD record: ord-78b250986b1a40148e5391644b3ec690
Source dataset: uspto-grants-2013_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08404869B2

Reaction notes

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