Isopropanol → HCID 178439727, compound

HRID 1952281Notes

Reaction equation

C([O:4][C:5]1[C:6](=[O:12])[CH:7]=[CH:8][C:9](=[O:11])[CH:10]=1)C=C.[CH3:13][C:14]1[CH:21]=[CH:20][C:17]([CH:18]=[CH2:19])=[CH:16][CH:15]=1.[CH:22](O)([CH3:24])[CH3:23]>>[CH2:24]([C:10]1[C:9](=[O:11])[C:8]2[CH:19]=[CH:18][C:17]3[C:20]([C:7]=2[C:6](=[O:12])[C:5]=1[OH:4])=[CH:21][C:14]([CH3:13])=[CH:15][CH:16]=3)[CH:22]=[CH2:23]

Participants

Reactant 3

HCID 3776Isopropanol

HCID 121611-Ethenyl-4-methylbenzene

HCID 469118002-[(Prop-2-en-1-yl)oxy]cyclohexa-2,5-diene-1,4-dione

Product 1

HCID 178439727HCID 178439727, compound

Procedure

2-Allyloxy-1,4-benzoquinone (6.56 g, 40 mM) and p-Methylstyrene (17.4 g, 0.10 M) were dissolved in 80 ml of isopropanol to give 2.3 g (8.3 mM) of 2-Allyl-3-hydroxy-6-methyl-1,4-phenanthrenequinone in the same manner as in Example 7.

Sources & evidence

ORD record: ord-11e892db88e647b58ad7b39258453529
Source dataset: uspto-grants-2013_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08404869B2

Reaction notes

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